Product ID:NALCO SOLUTION S0125
MSDS Date:11/18/1985
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKRNL

Emergency Phone: (312) 920-1510

Info Phone: (312) 981-9500

Preparer: JOHN J. KASPER, MSC., TOX

Cage: TO721

Telephone: (312) 981-9500

Cage: TO721

SODIUM BISULFATE

CAS: 7681-38-1

RTECS: VZ1860000

Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRIMARY ROUTE(S) OF EXPOSURE: EYE,
SKIN. EYE CONTACT: CAN CAUSE ACIDIC TYPE BURNS. SKIN CONTACT:
CORROSIVE TO SKIN, POSSIBLY RESULTING IN 3RD DEGREE BURNS DEPENDING
ON LENGTH OF EXPOSURE & ON FIRST AI D ACTION GIVEN.
Effects of Overexposure:A REVIEW OF AVAILABLE DATA DOES NOT IDENTIFY
ANY SYMPTOMS FROM EXPOSURE.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OR EXISTING CONDITIONS.

First Aid:EYES: IMMED FLUSH FOR AT LEAST 15 MIN WHILE HOLDING EYELIDS
OPEN. CALL PHYSICIAN AT ONCE. SKIN: FLUSH W/WATER FOR AT LEAST 15
MIN. INGEST: DO NOT INDUCE VOMITING. GIVE WATER. CALL A PHYSICIAN.
INHALAT ION: REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT A
PHYSICIAN IMMEDIATELY . NOTE TO PHYSICIAN: NO SPECIFIC ANTIDOTE
KNOWN. BASED ON INDIVIDUAL REACTIONS OF PATIENT, PHYSICIAN'S
JUDGEMENT SHOU LD BE USED TO CONTROL SYMPTOMS & CLINICAL CONDITION.
CAUTION: IF UNCONCIOUS, HAVING TROUBLE BREATHING OR IN CONVULSIONS,
DO NOT INDUCE VOMITING OR GIVE WATER. NOTE TO PHYSICIAN: PROBABLE
MUCOSAL DAMAG E (SUPPLEMENTAL DATA).

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NOT
APPLICABLE (MFR).
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY EVOLVE SO*X UNDER FIRE CONDITIONS.
CONTACT WITH WATER WILL GENERATE SULFURIC ACID.

Spill Release Procedures:SOLID SPILLS: SWEEP OR VACUUM UP & RECLAIM
INTO RECOVERY OR SALVAGE DRUMS FOR DISPOSAL. WEAR PROTECTIVE EQUIP
SPECIFIED. REFER TO CERCLA IN FEDERAL REGULATORY SECTION.
Neutralizing Agent:DISSOLVE IN WATER.THEN NEUTRALIZE WITH SODA ASH OR
SODIUM BICARBONATE. ACID SOLUTIONS SHOULD(OTHER PRECAUTIONS).

Handling and Storage Precautions:N/P. NEUTRALIZING AGENT: BE
NEUTRALIZED BEFORE BEING DISCHARGED TO A SANITARY SEWER.
ALTERNATELY, AN ACID SOLUTION MAY BE DISPOSED INTO A WASTE
TREATMENT PLANT WHICH HAS A PH CONTROL SYSTEM IN OPERATI ON.
Other Precautions:WARNING: CAUSES BURNS. AVOID CONTACT WITH SKIN AND
EYES. DO NOT TAKE INTERNALLY.

Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN . FOR LARGE SPILLS/ENTRY INTO LARGE TANKS,
VESSELS OR ENCLOSED SMALL SPACES W/INADEQUATE VENT, A
PRESSURE-DEMAND, SELF-CONTAIN ED BREATHING APPARATUS IS
RECOMMENDED.
Ventilation:IF SIGNIFICANT DUSTING OCCURS, LOCAL EXHAUST VENTILATION IS
RECOMMENDED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES & FULL FACESHIELD
.
Other Protective Equipment:EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR GLOVES, APRONS, SLICKER SUIT TO AVOID SKIN CONTACT.
(ANSI Z 87.1 REQUIREMENTS & SELECTION OF GLOVES, GOGGLES, SHOES,
ETC.).
Work Hygienic Practices:IF CLOTHING CONTAMINATED, REMOVE & THOROUGHLY
WASH AFFECTED AREA. LAUNDER CONTAM CLOTHING BEFORE REUSE. DISCARD
CONTAMINATED SHOES & LEATHER ITEMS.
Supplemental Safety and Health
FIRST AID: MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE. MEASURES
AGAINST CIRCULATORY SHOCK, RESPIRATORY DEPRESSION AND CONVULSIONS
MAY BE NEEDED. PHYSICAL/CHEMICAL: THESE PHYSICAL DATA ARE TYPICAL V
ALUES FOR THIS PRODUCT.

Melt/Freeze Pt:=170.C, 338.F
M.P/F.P Text:ASTM D-2117
Spec Gravity:0.5 ASTM D-1298
Solubility in Water:COMPLETELY
Appearance and Odor:OFF-WHITE PARTICLES. ODOR: NONE.

CALCIUM HYPOCHLORITE. AVOID ALKALINE MATLS (E.G: AMMONIA & ITS
SOLUTIONS, CARBONATES, SODIUM HYDROXIDE (CAUSTIC), POTASSIUM
HYDROXIDE, CALCIUM HYDROXIDE (LIME), CYANIDES, SULFIDES,
HYPOCHLORITES, CHLORITES) WHICH CAN GENERA
Hazardous Decomposition Products:IN EVENT OF COMBUSTION, CO*2, SO*X,
MAY BE FORMED. DO NOT BREATHE SMOKE OR FUMES. WEAR SUITABLE
PROTECTIVE EQUIPMENT.

Waste Disposal Methods:IF PRODUCT BECOMES WASTE, IT DOESN'T MEET
CRITERIA OF HAZ WASTE AS DEFINED UNDER RCRA 40 CFR 261, SINCE IT
DOESN'T HAVE CHARACTERISTICS OF SUBPART C, (I.E., DOO1 THRU D017)
NOR IS IT LISTED UNDER SUBP ART D. DISSOLVE IN WATER. THEN
NEUTRALIZE W/SODA ASH/SODIUM BICARBONATE. ACID SOLUTIONS SHLD BE
NEUT RALIZED BEFORE BEING DISCHARGED (OTHER INFO)

Toxicological Information:ACUTE TOXICITY STUDIES HAVE BEEN CONDUCTED ON
THIS PRODUCT. RESULTS ARE: PRIMARY SKIN IRRITATION TEST (ALBINO
RABBITS): SKIN IRRITATION INDEX DRAIZE RATING: 8.0/8.0 CORROSIVE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ENVIRONMENTAL INFORMATION: IF RELEASED INTO THE ENVIRONMENT,
REFER TO FEDERAL REGULATORY SECTION.

Transport Information:DOT PROPER SHIPPING NAME/HAZARD CODE - SODIUM
HYDROGEN SULFATE, SOLID, ORM-B UN 1821. IN CASE OF TRANSPORTATION
ACCIDENTS, CALL THE FOLLOWING 24-HOUR TELEPHONE NUMBER
(312-920-1510).

SARA Title III Information:FEDERAL REGULATORY: FEDERAL WATER POLLUTION
CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (FORMERLY SEC. 307),
40CFR 116 (FORMERLY SEC. 311): NONE OF THE INGREDIENTS ARE
SPECIFICALLY LISTED. CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR
61, SECTION 112: THIS PRODUCT DOES NOT CONTAIN INGREDIENTS COVERED
BY THE CLEAN AIR ACT.
Federal Regulatory Information:OSHA'S HAZARD COMMUNICATION RULE, 29
CFR 1910.1200: BASED ON OUR HAZARD EVALUATION, THE FOLLOWING
INGREDIENT IN THIS PRODUCT IS HAZARDOUS &THE REASON IS SHOWN BELOW:
SODIUM BISULFATE-CORROSIVE. CERC LA/SUPERFUND, 40 CFR 117, 302:
NOTIFICATION OF SPILLS OF THIS PRODUCT IS NOT REQUIRED. TOXIC
SUBSTANCES CONTROL ACT (TSCA):THE CHEMICAL INGREDIENTS IN THIS
PRODUCT ARE ON THE 8(B) INVENTORY LIST (40 C FR 710). RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261 SUBPART C & D: IF
PRODUCT BECOMES A WASTE, IT DOES NOT MEET THE CRITERIA OF A HAZ
WASTE (SEE SARA TITLE III).
State Regulatory Information:MICHIGAN CRITICAL MATERIALS: PRODUCT DOES
NOT CONTAIN INGREDIENTS LISTED ON THE MICHIGAN CRITICAL MATERIALS
REGISTER. STATE RIGHT-TO-KNOW LAWS: REGULATED IN THOSE STATES USING
TLV FOR SODIUM BISULFATE AS A CRITERIA FOR LISTING.